Aiming at efficient data acquisition, real-time precise positioning and attitude measurement problems of geostress low-frequency electromagnetic monitoring, real-time data acquisition system was designed and implemented in combination with positioning and attitude measurement module. The hardware system took ARM microprocessor (S3C6410) as control core based on embedded Linux. The hardware and software design architecture were introduced in detail. In addition, the algorithm of positioning and attitude measurement characteristics data extraction was proposed. Monitoring terminal of data acquisition and processing was designed using Qt/Embedded GUI programming technique based on LCD (Liquid Crystal Display) and achieved human-computer interaction. Meanwhile, the required data could be real-time stored to SD card. The results of system debugging and actual field experiments indicate that the system can complete the positioning and attitude data acquisition and processing, effectively solve the problem of real-time positioning for in-situ monitoring. It also can realize geostress low-frequency electromagnetic monitoring with high-speed, real-time and high reliability.